Iron(III)-Mediated Rapid Radical-Type Three-Component Deuteration of Quinoxalinones With Olefins and NaBD(4)

Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD(4) is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones. In this transformation, a radical pathway is involved according...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Wanmei, Cai, Heng, Huang, Lin, He, Lei, Zhang, Yilan, Xu, Jun, Zhang, Pengfei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7417774/
https://www.ncbi.nlm.nih.gov/pubmed/32850638
http://dx.doi.org/10.3389/fchem.2020.00606
Descripción
Sumario:Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD(4) is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones. In this transformation, a radical pathway is involved according to the results of control experiments.

Ejemplares similares