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Silicon–silicon π single bond

A carbon–carbon double bond consists of a σ bond and a π bond. Recently, the concept of a π single bond, where a π bond is not accompanied by a σ bond, has been proposed in diradicals containing carbon and heteroatom radical centers. Here we report a closed-shell compound having a silicon–silicon π...

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Detalles Bibliográficos
Autores principales: Kyushin, Soichiro, Kurosaki, Yoshikuni, Otsuka, Kyohei, Imai, Haruna, Ishida, Shintaro, Kyomen, Toru, Hanaya, Minoru, Matsumoto, Hideyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7419521/
https://www.ncbi.nlm.nih.gov/pubmed/32782244
http://dx.doi.org/10.1038/s41467-020-17815-z