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Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity

Nanostructured TiO(2) coatings were successfully formed on polyethylene terephthalate (PET) films and fluorine-doped tin oxide (FTO) films in aqueous solutions. They contained an assembly of nanoneedles that grow perpendicular to the films. The surface area of the coatings on PET films reached aroun...

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Autor principal: Masuda, Yoshitake
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7419526/
https://www.ncbi.nlm.nih.gov/pubmed/32782341
http://dx.doi.org/10.1038/s41598-020-70525-w
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author Masuda, Yoshitake
author_facet Masuda, Yoshitake
author_sort Masuda, Yoshitake
collection PubMed
description Nanostructured TiO(2) coatings were successfully formed on polyethylene terephthalate (PET) films and fluorine-doped tin oxide (FTO) films in aqueous solutions. They contained an assembly of nanoneedles that grow perpendicular to the films. The surface area of the coatings on PET films reached around 284 times that of a bare PET film. Micro-, nano-, or subnanosized surface roughness and inside pores contributed to the high nitrogen adsorption. The coatings on FTO films showed an acetaldehyde removal rate of 2.80 μmol/h; this value is similar to those of commercial products certified by the Photocatalysis Industry Association of Japan. The rate increased greatly to 10.16 μmol/h upon annealing in air at 500 °C for 4 h; this value exceeded those of commercial products. Further, the coatings showed a NO(x) removal rate of 1.04 μmol/h; this value is similar to those of commercial products. The rate decreased to 0.42 μmol/h upon annealing. NO(x) removal was affected by the photocatalyst’s surface area rather than its crystallinity.
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spelling pubmed-74195262020-08-13 Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity Masuda, Yoshitake Sci Rep Article Nanostructured TiO(2) coatings were successfully formed on polyethylene terephthalate (PET) films and fluorine-doped tin oxide (FTO) films in aqueous solutions. They contained an assembly of nanoneedles that grow perpendicular to the films. The surface area of the coatings on PET films reached around 284 times that of a bare PET film. Micro-, nano-, or subnanosized surface roughness and inside pores contributed to the high nitrogen adsorption. The coatings on FTO films showed an acetaldehyde removal rate of 2.80 μmol/h; this value is similar to those of commercial products certified by the Photocatalysis Industry Association of Japan. The rate increased greatly to 10.16 μmol/h upon annealing in air at 500 °C for 4 h; this value exceeded those of commercial products. Further, the coatings showed a NO(x) removal rate of 1.04 μmol/h; this value is similar to those of commercial products. The rate decreased to 0.42 μmol/h upon annealing. NO(x) removal was affected by the photocatalyst’s surface area rather than its crystallinity. Nature Publishing Group UK 2020-08-11 /pmc/articles/PMC7419526/ /pubmed/32782341 http://dx.doi.org/10.1038/s41598-020-70525-w Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Masuda, Yoshitake
Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity
title Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity
title_full Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity
title_fullStr Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity
title_full_unstemmed Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity
title_short Bio-inspired mineralization of nanostructured TiO(2) on PET and FTO films with high surface area and high photocatalytic activity
title_sort bio-inspired mineralization of nanostructured tio(2) on pet and fto films with high surface area and high photocatalytic activity
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7419526/
https://www.ncbi.nlm.nih.gov/pubmed/32782341
http://dx.doi.org/10.1038/s41598-020-70525-w
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