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Energy storing bricks for stationary PEDOT supercapacitors

Fired brick is a universal building material, produced by thousand-year-old technology, that throughout history has seldom served any other purpose. Here, we develop a scalable, cost-effective and versatile chemical synthesis using a fired brick to control oxidative radical polymerization and deposi...

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Detalles Bibliográficos
Autores principales: Wang, Hongmin, Diao, Yifan, Lu, Yang, Yang, Haoru, Zhou, Qingjun, Chrulski, Kenneth, D’Arcy, Julio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7419536/
https://www.ncbi.nlm.nih.gov/pubmed/32782258
http://dx.doi.org/10.1038/s41467-020-17708-1
Descripción
Sumario:Fired brick is a universal building material, produced by thousand-year-old technology, that throughout history has seldom served any other purpose. Here, we develop a scalable, cost-effective and versatile chemical synthesis using a fired brick to control oxidative radical polymerization and deposition of a nanofibrillar coating of the conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT). A fired brick’s open microstructure, mechanical robustness and ~8 wt% α-Fe(2)O(3) content afford an ideal substrate for developing electrochemical PEDOT electrodes and stationary supercapacitors that readily stack into modules. Five-minute epoxy serves as a waterproof case enabling the operation of our supercapacitors while submerged underwater and a gel electrolyte extends cycling stability to 10,000 cycles with ~90% capacitance retention.