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Fulvalene as a platform for the synthesis of a dimetallic dysprosocenium single-molecule magnet

The dinucleating fulvalenyl ligand [1,1′,3,3′-(C(5)(t)Bu(2)H(2))(2)](2–) (Fv(tttt)) was used to synthesize the dimetallic dysprosocenium cation [{Dy(η(5)-Cp*)}(2)(μ-BH(4))(η(5):η(5)-Fv(tttt))](+) (3) as the salt of [B(C(6)F(5))(4)](–) (Cp* = C(5)Me(5)). Compound [3][B(C(6)F(5))(4)] was obtained usin...

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Detalles Bibliográficos
Autores principales: He, Mian, Guo, Fu-Sheng, Tang, Jinkui, Mansikkamäki, Akseli, Layfield, Richard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7422961/
https://www.ncbi.nlm.nih.gov/pubmed/32832050
http://dx.doi.org/10.1039/d0sc02033h

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