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Aluminum porphyrins with quaternary ammonium halides as catalysts for copolymerization of cyclohexene oxide and CO(2): metal–ligand cooperative catalysis
Bifunctional Al(III) porphyrins with quaternary ammonium halides, 2-Cl and 2-Br, worked as excellent catalysts for the copolymerization of cyclohexene oxide (CHO) and CO(2) at 120 °C. Turnover frequency (TOF) and turnover number (TON) reached 10 000 h(–1) and 55 000, respectively, and poly(cyclohexe...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7425082/ https://www.ncbi.nlm.nih.gov/pubmed/32864082 http://dx.doi.org/10.1039/d0sc01609h |