Ultra-Weak Chemiluminescence Enhanced by Cerium-Doped LaF(3) Nanoparticles: A Potential Nitrite Analysis Method

In this work, cerium-doped LaF(3) nanoparticles (LaF(3):Ce NPs) were successfully synthesized and characterized. Its chemiluminescence (CL) property was studied, and it was amazingly found that it intensely enhanced the ultra-weak CL of the NaNO(2)-H(2)O(2) system. The CL mechanism was systematicall...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yufei, Wang, Yanran, Huang, Chunxia, Chen, Tianyou, Wu, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7426363/
https://www.ncbi.nlm.nih.gov/pubmed/32850655
http://dx.doi.org/10.3389/fchem.2020.00639
Descripción
Sumario:In this work, cerium-doped LaF(3) nanoparticles (LaF(3):Ce NPs) were successfully synthesized and characterized. Its chemiluminescence (CL) property was studied, and it was amazingly found that it intensely enhanced the ultra-weak CL of the NaNO(2)-H(2)O(2) system. The CL mechanism was systematically investigated and suggested to be the recombination of electron-injected and hole-injected LaF(3):Ce NPs. The new CL system was developed to be a facile, original, and direct method for nitrite analysis. Experimental conditions were optimized and then a satisfactory linear relationship between CL intensity and nitrite concentration was obtained. This work introduced a new pathway for the research and application of traditional fluoride NPs doped with RE(3+).

Ejemplares similares