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Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier
By reaction of HCl and the tertiary amine HA324, an ionic liquid denoted HA324H(+)Cl(−) was generated and used in the transport of indium(III) from HCl solutions. Metal transport experiments were carried out with a supported liquid membrane, and several variables affecting the permeation of indium(I...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7431576/ https://www.ncbi.nlm.nih.gov/pubmed/32807829 http://dx.doi.org/10.1038/s41598-020-70968-1 |
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author | Alguacil, Francisco José López, Félix Antonio |
author_facet | Alguacil, Francisco José López, Félix Antonio |
author_sort | Alguacil, Francisco José |
collection | PubMed |
description | By reaction of HCl and the tertiary amine HA324, an ionic liquid denoted HA324H(+)Cl(−) was generated and used in the transport of indium(III) from HCl solutions. Metal transport experiments were carried out with a supported liquid membrane, and several variables affecting the permeation of indium(III) across the membrane were tested: stirring speed, metal and acid concentrations in the feed solutions and the carrier concentration in the supported organic solution. The metal transport results were also compared with those obtained using different carriers in the solid support. A model that described indium(III) transport across the membrane was proposed, and the corresponding diffusional parameters were estimated. |
format | Online Article Text |
id | pubmed-7431576 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-74315762020-08-18 Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier Alguacil, Francisco José López, Félix Antonio Sci Rep Article By reaction of HCl and the tertiary amine HA324, an ionic liquid denoted HA324H(+)Cl(−) was generated and used in the transport of indium(III) from HCl solutions. Metal transport experiments were carried out with a supported liquid membrane, and several variables affecting the permeation of indium(III) across the membrane were tested: stirring speed, metal and acid concentrations in the feed solutions and the carrier concentration in the supported organic solution. The metal transport results were also compared with those obtained using different carriers in the solid support. A model that described indium(III) transport across the membrane was proposed, and the corresponding diffusional parameters were estimated. Nature Publishing Group UK 2020-08-17 /pmc/articles/PMC7431576/ /pubmed/32807829 http://dx.doi.org/10.1038/s41598-020-70968-1 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
spellingShingle | Article Alguacil, Francisco José López, Félix Antonio Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier |
title | Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier |
title_full | Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier |
title_fullStr | Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier |
title_full_unstemmed | Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier |
title_short | Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H(+)Cl(−) ionic liquid as the carrier |
title_sort | dispersion-free extraction of in(iii) from hcl solutions using a supported liquid membrane containing the ha324h(+)cl(−) ionic liquid as the carrier |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7431576/ https://www.ncbi.nlm.nih.gov/pubmed/32807829 http://dx.doi.org/10.1038/s41598-020-70968-1 |
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