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Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum–nitrogen heterocycles

Aside from simple Lewis acid–base chemistry, the reaction chemistry of aluminacyclopentadienes, which are commonly referred to as aluminoles or simply alumoles, remains relatively underdeveloped. To date, few attempts to extend their inherent insertion and cycloaddition reactivity to the constructio...

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Detalles Bibliográficos
Autores principales: Drescher, Regina, Lin, Shujuan, Hofmann, Alexander, Lenczyk, Carsten, Kachel, Stephanie, Krummenacher, Ivo, Lin, Zhenyang, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7444475/
https://www.ncbi.nlm.nih.gov/pubmed/32874499
http://dx.doi.org/10.1039/d0sc02032j