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Methylbismuth: an organometallic bismuthinidene biradical

We report the generation, spectroscopic characterization, and computational analysis of the first free (non-stabilized) organometallic bismuthinidene, BiMe. The title compound was generated in situ from BiMe(3) by controlled homolytic Bi–C bond cleavage in the gas phase. Its electronic structure was...

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Detalles Bibliográficos
Autores principales:	Mukhopadhyay, Deb Pratim, Schleier, Domenik, Wirsing, Sara, Ramler, Jacqueline, Kaiser, Dustin, Reusch, Engelbert, Hemberger, Patrick, Preitschopf, Tobias, Krummenacher, Ivo, Engels, Bernd, Fischer, Ingo, Lichtenberg, Crispin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7450715/ https://www.ncbi.nlm.nih.gov/pubmed/32874526 http://dx.doi.org/10.1039/d0sc02410d

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