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Copper(I)-catalyzed diastereo- and enantio-selective construction of optically pure exocyclic allenes

Among about 150 identified allenic natural products, the exocyclic allenes constitute a major subclass. Substantial efforts are devoted to the construction of axially chiral allenes, however, the strategies to prepare chiral exocyclic allenes are still rare. Herein, we show an efficient strategy for...

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Detalles Bibliográficos
Autores principales: He, Cheng-Yu, Tan, Yun-Xuan, Wang, Xin, Ding, Rui, Wang, Yi-Fan, Wang, Feng, Gao, Dingding, Tian, Ping, Lin, Guo-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7453021/
https://www.ncbi.nlm.nih.gov/pubmed/32855405
http://dx.doi.org/10.1038/s41467-020-18136-x