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Copper(I)-catalyzed diastereo- and enantio-selective construction of optically pure exocyclic allenes
Among about 150 identified allenic natural products, the exocyclic allenes constitute a major subclass. Substantial efforts are devoted to the construction of axially chiral allenes, however, the strategies to prepare chiral exocyclic allenes are still rare. Herein, we show an efficient strategy for...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7453021/ https://www.ncbi.nlm.nih.gov/pubmed/32855405 http://dx.doi.org/10.1038/s41467-020-18136-x |