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Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes
[Image: see text] A series of PNP zinc pincer complexes capable of bond activation via aromatization/dearomatization metal–ligand cooperation (MLC) were prepared and characterized. Reversible heterolytic N–H and H–H bond activation by MLC is shown, in which hemilability of the phosphorus linkers pla...
Autores principales: | Rauch, Michael, Kar, Sayan, Kumar, Amit, Avram, Liat, Shimon, Linda J. W., Milstein, David |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7453403/ https://www.ncbi.nlm.nih.gov/pubmed/32786799 http://dx.doi.org/10.1021/jacs.0c05500 |
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