Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions

A silver‐triggered heterogeneous Pd‐catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one‐pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride...

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Autores principales: Li, Man‐Bo, Yang, Ying, Rafi, Abdolrahim A., Oschmann, Michael, Grape, Erik Svensson, Inge, A. Ken, Córdova, Armando, Bäckvall, Jan‐E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7463174/
https://www.ncbi.nlm.nih.gov/pubmed/32091647
http://dx.doi.org/10.1002/anie.202001809
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author Li, Man‐Bo
Yang, Ying
Rafi, Abdolrahim A.
Oschmann, Michael
Grape, Erik Svensson
Inge, A. Ken
Córdova, Armando
Bäckvall, Jan‐E.
author_facet Li, Man‐Bo
Yang, Ying
Rafi, Abdolrahim A.
Oschmann, Michael
Grape, Erik Svensson
Inge, A. Ken
Córdova, Armando
Bäckvall, Jan‐E.
author_sort Li, Man‐Bo
collection PubMed
description A silver‐triggered heterogeneous Pd‐catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one‐pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd‐AmP‐CNC, thereby generating highly active Pd(II), which results in high efficiency of the heterogeneous catalytic system.
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spelling pubmed-74631742020-09-04 Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions Li, Man‐Bo Yang, Ying Rafi, Abdolrahim A. Oschmann, Michael Grape, Erik Svensson Inge, A. Ken Córdova, Armando Bäckvall, Jan‐E. Angew Chem Int Ed Engl Communications A silver‐triggered heterogeneous Pd‐catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one‐pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd‐AmP‐CNC, thereby generating highly active Pd(II), which results in high efficiency of the heterogeneous catalytic system. John Wiley and Sons Inc. 2020-04-07 2020-06-22 /pmc/articles/PMC7463174/ /pubmed/32091647 http://dx.doi.org/10.1002/anie.202001809 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Li, Man‐Bo
Yang, Ying
Rafi, Abdolrahim A.
Oschmann, Michael
Grape, Erik Svensson
Inge, A. Ken
Córdova, Armando
Bäckvall, Jan‐E.
Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
title Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
title_full Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
title_fullStr Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
title_full_unstemmed Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
title_short Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
title_sort silver‐triggered activity of a heterogeneous palladium catalyst in oxidative carbonylation reactions
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7463174/
https://www.ncbi.nlm.nih.gov/pubmed/32091647
http://dx.doi.org/10.1002/anie.202001809
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