A Facile Strategy to Fabricate Antistatic Polyamide 1012/Multi-Walled Carbon Nanotube Pipes for Fuel Delivery Applications

Developing antistatic long chain polyamide (LCPA) resins and fabricating the corresponding fuel pipes are challenges but necessary. Herein, a facile but effective strategy was put forward to fabricate LCPA resins with a superior conductivity, meeting the requirements of electrostatic sub-conductors. The strategy was based on, first, the incorporation of a large amount (15 wt%) of multi-walled carbon nanotubes (MWCNTs) into a polyamide 1012 (PA1012) matrix as a master batch, which formed a dense conductive network. Subsequently, it was diluted with PA1012 granules to produce base resins, and the reprocessed nanocomposites with a critical content of MWCNTs (3 wt%) could generate an effectively interconnected conductive network, with sparse and thinning features. Using the base resins, fuel pipes for automobiles, petrol stations and high pressure applications were successfully fabricated, where the thin conductive network was transformed into a thick one due to external field-induced re-agglomeration of MWCNTs. In this way, the obtained fuel pipes combined excellent conductive and barrier properties, and mechanical properties at high and low temperatures. These comprehensive properties also arose from the uniform dispersion of MWCNTs in an LCPA matrix, even without coupling agents; the attractive interaction between MWCNTs and the polyamide chains contributed to their strong interface adhesion. Thus, this research provides a versatile approach to fabricating antistatic LCPA resins, which will certainly extend their application to vehicle fuel systems.