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CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery
N-doped porous carbon encapsulated NiO/Ni composite nanomaterials (N-doped NiO/Ni@C) was successfully obtained by a one-step solution combustion method. This study demonstrates a one-step combustion method to synthesize n-doped porous carbon encapsulated NiO/Ni composite nanomaterials, using carbon...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7466505/ https://www.ncbi.nlm.nih.gov/pubmed/32751783 http://dx.doi.org/10.3390/nano10081502 |
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author | Li, Yayong Xu, Chunxiao Liu, Kaiyuan Chen, Pengwan Gao, Xin |
author_facet | Li, Yayong Xu, Chunxiao Liu, Kaiyuan Chen, Pengwan Gao, Xin |
author_sort | Li, Yayong |
collection | PubMed |
description | N-doped porous carbon encapsulated NiO/Ni composite nanomaterials (N-doped NiO/Ni@C) was successfully obtained by a one-step solution combustion method. This study demonstrates a one-step combustion method to synthesize n-doped porous carbon encapsulated NiO/Ni composite nanomaterials, using carbon dioxide as the carbon source, nickel nitrate as the nickel source, and hydrazine hydrate as the reaction solution. Spherical NiO nanoparticles with a particle size of 20 nm were uniformly distributed in the carbon matrix. The load of NiO/Ni can be controlled by the amount of nickel nitrate. The range of carbon content of recovered samples is 69–87 at%. The content of incorporated nitrogen for recovered samples is 1.94 at%. As the anode of lithium ion battery, the composite material exhibits high capacity, excellent multiplier performance and stable circulation performance. N-doped NiO/Ni@C-2 was applied to lithium ion batteries, and its reversible capacity maximum is 980 mAh g(−1) after 100 cycles at the current density of 0.1 A g(−1). Its excellent electrochemical properties imply its high potential application for high-performance lithium-ion battery anode materials. |
format | Online Article Text |
id | pubmed-7466505 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-74665052020-09-14 CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery Li, Yayong Xu, Chunxiao Liu, Kaiyuan Chen, Pengwan Gao, Xin Nanomaterials (Basel) Article N-doped porous carbon encapsulated NiO/Ni composite nanomaterials (N-doped NiO/Ni@C) was successfully obtained by a one-step solution combustion method. This study demonstrates a one-step combustion method to synthesize n-doped porous carbon encapsulated NiO/Ni composite nanomaterials, using carbon dioxide as the carbon source, nickel nitrate as the nickel source, and hydrazine hydrate as the reaction solution. Spherical NiO nanoparticles with a particle size of 20 nm were uniformly distributed in the carbon matrix. The load of NiO/Ni can be controlled by the amount of nickel nitrate. The range of carbon content of recovered samples is 69–87 at%. The content of incorporated nitrogen for recovered samples is 1.94 at%. As the anode of lithium ion battery, the composite material exhibits high capacity, excellent multiplier performance and stable circulation performance. N-doped NiO/Ni@C-2 was applied to lithium ion batteries, and its reversible capacity maximum is 980 mAh g(−1) after 100 cycles at the current density of 0.1 A g(−1). Its excellent electrochemical properties imply its high potential application for high-performance lithium-ion battery anode materials. MDPI 2020-07-31 /pmc/articles/PMC7466505/ /pubmed/32751783 http://dx.doi.org/10.3390/nano10081502 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Li, Yayong Xu, Chunxiao Liu, Kaiyuan Chen, Pengwan Gao, Xin CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery |
title | CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery |
title_full | CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery |
title_fullStr | CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery |
title_full_unstemmed | CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery |
title_short | CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery |
title_sort | co(2) conversion into n-doped porous carbon-encapsulated nio/ni composite nanomaterials as outstanding anode material of li battery |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7466505/ https://www.ncbi.nlm.nih.gov/pubmed/32751783 http://dx.doi.org/10.3390/nano10081502 |
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