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CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery

N-doped porous carbon encapsulated NiO/Ni composite nanomaterials (N-doped NiO/Ni@C) was successfully obtained by a one-step solution combustion method. This study demonstrates a one-step combustion method to synthesize n-doped porous carbon encapsulated NiO/Ni composite nanomaterials, using carbon...

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Autores principales: Li, Yayong, Xu, Chunxiao, Liu, Kaiyuan, Chen, Pengwan, Gao, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7466505/
https://www.ncbi.nlm.nih.gov/pubmed/32751783
http://dx.doi.org/10.3390/nano10081502
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author Li, Yayong
Xu, Chunxiao
Liu, Kaiyuan
Chen, Pengwan
Gao, Xin
author_facet Li, Yayong
Xu, Chunxiao
Liu, Kaiyuan
Chen, Pengwan
Gao, Xin
author_sort Li, Yayong
collection PubMed
description N-doped porous carbon encapsulated NiO/Ni composite nanomaterials (N-doped NiO/Ni@C) was successfully obtained by a one-step solution combustion method. This study demonstrates a one-step combustion method to synthesize n-doped porous carbon encapsulated NiO/Ni composite nanomaterials, using carbon dioxide as the carbon source, nickel nitrate as the nickel source, and hydrazine hydrate as the reaction solution. Spherical NiO nanoparticles with a particle size of 20 nm were uniformly distributed in the carbon matrix. The load of NiO/Ni can be controlled by the amount of nickel nitrate. The range of carbon content of recovered samples is 69–87 at%. The content of incorporated nitrogen for recovered samples is 1.94 at%. As the anode of lithium ion battery, the composite material exhibits high capacity, excellent multiplier performance and stable circulation performance. N-doped NiO/Ni@C-2 was applied to lithium ion batteries, and its reversible capacity maximum is 980 mAh g(−1) after 100 cycles at the current density of 0.1 A g(−1). Its excellent electrochemical properties imply its high potential application for high-performance lithium-ion battery anode materials.
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spelling pubmed-74665052020-09-14 CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery Li, Yayong Xu, Chunxiao Liu, Kaiyuan Chen, Pengwan Gao, Xin Nanomaterials (Basel) Article N-doped porous carbon encapsulated NiO/Ni composite nanomaterials (N-doped NiO/Ni@C) was successfully obtained by a one-step solution combustion method. This study demonstrates a one-step combustion method to synthesize n-doped porous carbon encapsulated NiO/Ni composite nanomaterials, using carbon dioxide as the carbon source, nickel nitrate as the nickel source, and hydrazine hydrate as the reaction solution. Spherical NiO nanoparticles with a particle size of 20 nm were uniformly distributed in the carbon matrix. The load of NiO/Ni can be controlled by the amount of nickel nitrate. The range of carbon content of recovered samples is 69–87 at%. The content of incorporated nitrogen for recovered samples is 1.94 at%. As the anode of lithium ion battery, the composite material exhibits high capacity, excellent multiplier performance and stable circulation performance. N-doped NiO/Ni@C-2 was applied to lithium ion batteries, and its reversible capacity maximum is 980 mAh g(−1) after 100 cycles at the current density of 0.1 A g(−1). Its excellent electrochemical properties imply its high potential application for high-performance lithium-ion battery anode materials. MDPI 2020-07-31 /pmc/articles/PMC7466505/ /pubmed/32751783 http://dx.doi.org/10.3390/nano10081502 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Li, Yayong
Xu, Chunxiao
Liu, Kaiyuan
Chen, Pengwan
Gao, Xin
CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery
title CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery
title_full CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery
title_fullStr CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery
title_full_unstemmed CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery
title_short CO(2) Conversion into N-Doped Porous Carbon-Encapsulated NiO/Ni Composite Nanomaterials as Outstanding Anode Material of Li Battery
title_sort co(2) conversion into n-doped porous carbon-encapsulated nio/ni composite nanomaterials as outstanding anode material of li battery
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7466505/
https://www.ncbi.nlm.nih.gov/pubmed/32751783
http://dx.doi.org/10.3390/nano10081502
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