Growth of Multiorientated Polycrystalline MoS(2) Using Plasma-Enhanced Chemical Vapor Deposition for Efficient Hydrogen Evolution Reactions

Molybdenum disulfide (MoS(2)) has attracted considerable attention as a promising electrocatalyst for the hydrogen evolution reaction (HER). However, the catalytic HER performance of MoS(2) is significantly limited by the few active sites and low electrical conductivity. In this study, the growth of multiorientated polycrystalline MoS(2) using plasma-enhanced chemical vapor deposition (PECVD) for the HER is achieved. The MoS(2) is synthesized by sulfurizing a sputtered pillar-shaped Mo film. The relatively low growth temperature during the PECVD process results in multiorientated MoS(2) with an expanded interlayer spacing of ~0.75 nm, which provides abundant active sites, a reduced Gibbs free energy of H adsorption, and enhanced intralayer conductivity. In HER applications, the PECVD-grown MoS(2) exhibits an overpotential value of 0.45 V, a Tafel slope of 76 mV dec(−1), and excellent stability in strong acidic media for 10 h. The high HER performance achieved in this study indicates that two-dimensional MoS(2) has potential as an electrocatalyst for next-generation energy technologies.