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Tweaking the Charge Transfer: Bonding Analysis of Bismuth(III) Complexes with a Flexidentate Phosphane Ligand
[Image: see text] To account for the charge transfer and covalent character in bonding between P and Bi centers, the electronic structures of [P(C(6)H(4)-o-CH(2)SCH(3))(3)BiCl(n)]((3–n)+) (n = 0–3) model species have been investigated computationally. On the basis of this survey a synthetic target c...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7467670/ https://www.ncbi.nlm.nih.gov/pubmed/32530279 http://dx.doi.org/10.1021/acs.inorgchem.0c00734 |