Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes

[Image: see text] A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, in...

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Autores principales: Dian, Longyang, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7467819/
https://www.ncbi.nlm.nih.gov/pubmed/32506912
http://dx.doi.org/10.1021/acs.orglett.0c01833
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author Dian, Longyang
Marek, Ilan
author_facet Dian, Longyang
Marek, Ilan
author_sort Dian, Longyang
collection PubMed
description [Image: see text] A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities.
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spelling pubmed-74678192020-09-03 Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes Dian, Longyang Marek, Ilan Org Lett [Image: see text] A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities. American Chemical Society 2020-06-08 2020-06-19 /pmc/articles/PMC7467819/ /pubmed/32506912 http://dx.doi.org/10.1021/acs.orglett.0c01833 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Dian, Longyang
Marek, Ilan
Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
title Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
title_full Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
title_fullStr Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
title_full_unstemmed Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
title_short Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
title_sort cobalt-catalyzed diastereoselective and enantioselective hydrosilylation of achiral cyclopropenes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7467819/
https://www.ncbi.nlm.nih.gov/pubmed/32506912
http://dx.doi.org/10.1021/acs.orglett.0c01833
work_keys_str_mv AT dianlongyang cobaltcatalyzeddiastereoselectiveandenantioselectivehydrosilylationofachiralcyclopropenes
AT marekilan cobaltcatalyzeddiastereoselectiveandenantioselectivehydrosilylationofachiralcyclopropenes

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