Sodium-Polyacrylate-Based Electrochemical Sensors for Highly Sensitive Detection of Gaseous Phenol at Room Temperature

[Image: see text] The detection of volatile organic compounds with electrochemical gas sensors is still very challenging regarding their sensitivity, selectivity, and operation at room temperature. There is a need for robust, sensitive, inexpensive, and yet easy-to-operate sensors for phenol and other phenolic compounds that function reliably under ambient conditions. Herein, we present a phenol gas sensor based on a combination of a semisolid, alkaline sodium polyacrylate, and commercial screen-printed electrodes. Sodium polyacrylate was employed as a multifunctional sensing material serving as a (i) gel-like electrolyte, (ii) accumulation milieu, and (iii) derivatization medium. Under ambient conditions, the sensor showed excellent sensitivity in the low ppbv (μg m(–3)) range, a good linear operation in the examined concentration range of 0.1–1.0 ppmv for up to 105 min accumulation, and low sensitivity toward examined interferences. The sensor also indicated a possibility to differentiate between several phenolic compounds based on their oxidation potential. Given its favorable electroanalytical performance, a strong application potential is envisioned in topical fields such as environmental monitoring, cultural heritage preservation, and occupational health and safety.