Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis

[Image: see text] Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl...

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Autores principales: Rossi-Ashton, James A., Clarke, Aimee K., Unsworth, William P., Taylor, Richard J. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7469205/
https://www.ncbi.nlm.nih.gov/pubmed/32905246
http://dx.doi.org/10.1021/acscatal.0c01923
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author Rossi-Ashton, James A.
Clarke, Aimee K.
Unsworth, William P.
Taylor, Richard J. K.
author_facet Rossi-Ashton, James A.
Clarke, Aimee K.
Unsworth, William P.
Taylor, Richard J. K.
author_sort Rossi-Ashton, James A.
collection PubMed
description [Image: see text] Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunable mediators in photoredox catalysis, highlighting how two distinct methods for phosphoranyl radical formation (radical addition and nucleophilic addition) can be used to generate versatile radical intermediates with diverse reactivity profiles.
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spelling pubmed-74692052020-09-04 Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis Rossi-Ashton, James A. Clarke, Aimee K. Unsworth, William P. Taylor, Richard J. K. ACS Catal [Image: see text] Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunable mediators in photoredox catalysis, highlighting how two distinct methods for phosphoranyl radical formation (radical addition and nucleophilic addition) can be used to generate versatile radical intermediates with diverse reactivity profiles. American Chemical Society 2020-06-05 2020-07-02 /pmc/articles/PMC7469205/ /pubmed/32905246 http://dx.doi.org/10.1021/acscatal.0c01923 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Rossi-Ashton, James A.
Clarke, Aimee K.
Unsworth, William P.
Taylor, Richard J. K.
Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis
title Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis
title_full Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis
title_fullStr Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis
title_full_unstemmed Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis
title_short Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis
title_sort phosphoranyl radical fragmentation reactions driven by photoredox catalysis
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7469205/
https://www.ncbi.nlm.nih.gov/pubmed/32905246
http://dx.doi.org/10.1021/acscatal.0c01923
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AT unsworthwilliamp phosphoranylradicalfragmentationreactionsdrivenbyphotoredoxcatalysis
AT taylorrichardjk phosphoranylradicalfragmentationreactionsdrivenbyphotoredoxcatalysis

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