Cargando…

An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions

The effect of the green ionic liquid compound, Quaternium-32 (Q-32), on the corrosion inhibition performance of reinforcement steel, in a simulated concrete pore solution, was investigated at different temperatures and pH values, using electrochemical impedance spectroscopy (EIS). The inhibition eff...

Descripción completa

Detalles Bibliográficos
Autores principales: Sliem, Mostafa H., Radwan, Ahmed Bahgat, Mohamed, Farida S., Alnuaimi, Nasser A., Abdullah, Aboubakr M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7471328/
https://www.ncbi.nlm.nih.gov/pubmed/32884011
http://dx.doi.org/10.1038/s41598-020-71222-4
_version_ 1783578757314904064
author Sliem, Mostafa H.
Radwan, Ahmed Bahgat
Mohamed, Farida S.
Alnuaimi, Nasser A.
Abdullah, Aboubakr M.
author_facet Sliem, Mostafa H.
Radwan, Ahmed Bahgat
Mohamed, Farida S.
Alnuaimi, Nasser A.
Abdullah, Aboubakr M.
author_sort Sliem, Mostafa H.
collection PubMed
description The effect of the green ionic liquid compound, Quaternium-32 (Q-32), on the corrosion inhibition performance of reinforcement steel, in a simulated concrete pore solution, was investigated at different temperatures and pH values, using electrochemical impedance spectroscopy (EIS). The inhibition efficiency was improved as the concentration of Q-32 and pH values were increased. However, it decreased as the temperature was raised. A Q-32 concentration of 20 µmol L(–1) exhibited a 94% inhibition efficiency at 20 °C. The adsorption isotherm was evaluated using EIS measurements, and it was found to obey the Langmuir isotherm. The surface topography was examined using an atomic force microscope and scanning electron microscope. The effect of the Q-32 concentration with the highest corrosion efficiency on the mechanical properties of the mortars was also explained by flexure and compression techniques.
format Online
Article
Text
id pubmed-7471328
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-74713282020-09-04 An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions Sliem, Mostafa H. Radwan, Ahmed Bahgat Mohamed, Farida S. Alnuaimi, Nasser A. Abdullah, Aboubakr M. Sci Rep Article The effect of the green ionic liquid compound, Quaternium-32 (Q-32), on the corrosion inhibition performance of reinforcement steel, in a simulated concrete pore solution, was investigated at different temperatures and pH values, using electrochemical impedance spectroscopy (EIS). The inhibition efficiency was improved as the concentration of Q-32 and pH values were increased. However, it decreased as the temperature was raised. A Q-32 concentration of 20 µmol L(–1) exhibited a 94% inhibition efficiency at 20 °C. The adsorption isotherm was evaluated using EIS measurements, and it was found to obey the Langmuir isotherm. The surface topography was examined using an atomic force microscope and scanning electron microscope. The effect of the Q-32 concentration with the highest corrosion efficiency on the mechanical properties of the mortars was also explained by flexure and compression techniques. Nature Publishing Group UK 2020-09-03 /pmc/articles/PMC7471328/ /pubmed/32884011 http://dx.doi.org/10.1038/s41598-020-71222-4 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Sliem, Mostafa H.
Radwan, Ahmed Bahgat
Mohamed, Farida S.
Alnuaimi, Nasser A.
Abdullah, Aboubakr M.
An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions
title An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions
title_full An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions
title_fullStr An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions
title_full_unstemmed An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions
title_short An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions
title_sort efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7471328/
https://www.ncbi.nlm.nih.gov/pubmed/32884011
http://dx.doi.org/10.1038/s41598-020-71222-4
work_keys_str_mv AT sliemmostafah anefficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT radwanahmedbahgat anefficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT mohamedfaridas anefficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT alnuaiminassera anefficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT abdullahaboubakrm anefficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT sliemmostafah efficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT radwanahmedbahgat efficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT mohamedfaridas efficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT alnuaiminassera efficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions
AT abdullahaboubakrm efficientgreenionicliquidforthecorrosioninhibitionofreinforcementsteelinneutralandalkalinehighlysalinesimulatedconcreteporesolutions