Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane

The title compounds, C(13)H(18)O(3)Si (1) and C(18)H(20)O(3)Si (2), represent functional­izable di­hydro­furan­ylsilanes, which permit substitution by a variety of nucleophiles. The crystal structures of 1 and 2 display weak inter­molecular C—H⋯O hydrogen-bonding inter­actions (qu­anti­fied by Hirsh...

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Autores principales: Krupp, Anna, Barth, Eva Rebecca, Seymen, Rana, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7472748/
https://www.ncbi.nlm.nih.gov/pubmed/32939310
http://dx.doi.org/10.1107/S2056989020011470
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author Krupp, Anna
Barth, Eva Rebecca
Seymen, Rana
Strohmann, Carsten
author_facet Krupp, Anna
Barth, Eva Rebecca
Seymen, Rana
Strohmann, Carsten
author_sort Krupp, Anna
collection PubMed
description The title compounds, C(13)H(18)O(3)Si (1) and C(18)H(20)O(3)Si (2), represent functional­izable di­hydro­furan­ylsilanes, which permit substitution by a variety of nucleophiles. The crystal structures of 1 and 2 display weak inter­molecular C—H⋯O hydrogen-bonding inter­actions (qu­anti­fied by Hirshfeld surface analysis), leading to a two-dimensional supra­molecular network for 1 and a one-dimensional supra­molecular network for 2. The crystal structures of 1 and 2 were refined both on the basis of the independent atom model (IAM) and the Hirshfeld atom refinement (HAR) approach, and the results are comparatively discussed.
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spelling pubmed-74727482020-09-15 Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane Krupp, Anna Barth, Eva Rebecca Seymen, Rana Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Research Communications The title compounds, C(13)H(18)O(3)Si (1) and C(18)H(20)O(3)Si (2), represent functional­izable di­hydro­furan­ylsilanes, which permit substitution by a variety of nucleophiles. The crystal structures of 1 and 2 display weak inter­molecular C—H⋯O hydrogen-bonding inter­actions (qu­anti­fied by Hirshfeld surface analysis), leading to a two-dimensional supra­molecular network for 1 and a one-dimensional supra­molecular network for 2. The crystal structures of 1 and 2 were refined both on the basis of the independent atom model (IAM) and the Hirshfeld atom refinement (HAR) approach, and the results are comparatively discussed. International Union of Crystallography 2020-08-28 /pmc/articles/PMC7472748/ /pubmed/32939310 http://dx.doi.org/10.1107/S2056989020011470 Text en © Krupp et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Krupp, Anna
Barth, Eva Rebecca
Seymen, Rana
Strohmann, Carsten
Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane
title Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane
title_full Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane
title_fullStr Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane
title_full_unstemmed Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane
title_short Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane
title_sort crystal structures, hirshfeld atom refinements and hirshfeld surface analyses of tris­(4,5-di­hydro­furan-2-yl)methyl­silane and tris­(4,5-di­hydro­furan-2-yl)phenyl­silane
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7472748/
https://www.ncbi.nlm.nih.gov/pubmed/32939310
http://dx.doi.org/10.1107/S2056989020011470
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