Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)

In the title complex mol­ecule, [Cu(C(11)H(11)NO(4))(CH(4)O)(H(2)O)], the Cu atom is coordinated in a distorted square-pyramidal geometry by a tridentate ligand synthesized from l-threonine and salicyl­aldehyde, one methanol mol­ecule and one water mol­ecule. In the crystal, the mol­ecules show intr...

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Detalles Bibliográficos
Autores principales: Katsuumi, Natsuki, Onami, Yuika, Pradhan, Sayantan, Haraguchi, Tomoyuki, Akitsu, Takashiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7472767/
https://www.ncbi.nlm.nih.gov/pubmed/32939315
http://dx.doi.org/10.1107/S2056989020011706
Descripción
Sumario:In the title complex mol­ecule, [Cu(C(11)H(11)NO(4))(CH(4)O)(H(2)O)], the Cu atom is coordinated in a distorted square-pyramidal geometry by a tridentate ligand synthesized from l-threonine and salicyl­aldehyde, one methanol mol­ecule and one water mol­ecule. In the crystal, the mol­ecules show intra- and inter­molecular O—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are H⋯H (49.4%) and H⋯O/O⋯H (31.3%) contacts.

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