Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)

In the title complex mol­ecule, [Cu(C(11)H(11)NO(4))(CH(4)O)(H(2)O)], the Cu atom is coordinated in a distorted square-pyramidal geometry by a tridentate ligand synthesized from l-threonine and salicyl­aldehyde, one methanol mol­ecule and one water mol­ecule. In the crystal, the mol­ecules show intr...

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Autores principales: Katsuumi, Natsuki, Onami, Yuika, Pradhan, Sayantan, Haraguchi, Tomoyuki, Akitsu, Takashiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7472767/
https://www.ncbi.nlm.nih.gov/pubmed/32939315
http://dx.doi.org/10.1107/S2056989020011706
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author Katsuumi, Natsuki
Onami, Yuika
Pradhan, Sayantan
Haraguchi, Tomoyuki
Akitsu, Takashiro
author_facet Katsuumi, Natsuki
Onami, Yuika
Pradhan, Sayantan
Haraguchi, Tomoyuki
Akitsu, Takashiro
author_sort Katsuumi, Natsuki
collection PubMed
description In the title complex mol­ecule, [Cu(C(11)H(11)NO(4))(CH(4)O)(H(2)O)], the Cu atom is coordinated in a distorted square-pyramidal geometry by a tridentate ligand synthesized from l-threonine and salicyl­aldehyde, one methanol mol­ecule and one water mol­ecule. In the crystal, the mol­ecules show intra- and inter­molecular O—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are H⋯H (49.4%) and H⋯O/O⋯H (31.3%) contacts.
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spelling pubmed-74727672020-09-15 Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II) Katsuumi, Natsuki Onami, Yuika Pradhan, Sayantan Haraguchi, Tomoyuki Akitsu, Takashiro Acta Crystallogr E Crystallogr Commun Research Communications In the title complex mol­ecule, [Cu(C(11)H(11)NO(4))(CH(4)O)(H(2)O)], the Cu atom is coordinated in a distorted square-pyramidal geometry by a tridentate ligand synthesized from l-threonine and salicyl­aldehyde, one methanol mol­ecule and one water mol­ecule. In the crystal, the mol­ecules show intra- and inter­molecular O—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are H⋯H (49.4%) and H⋯O/O⋯H (31.3%) contacts. International Union of Crystallography 2020-08-28 /pmc/articles/PMC7472767/ /pubmed/32939315 http://dx.doi.org/10.1107/S2056989020011706 Text en © Katsuumi et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Katsuumi, Natsuki
Onami, Yuika
Pradhan, Sayantan
Haraguchi, Tomoyuki
Akitsu, Takashiro
Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)
title Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)
title_full Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)
title_fullStr Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)
title_short Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido­benzyl­idene)threoninato-κ(3) O,N,O′]copper(II)
title_sort crystal structure and hirshfeld surface analysis of (aqua-κo)(methanol-κo)[n-(2-oxido­benzyl­idene)threoninato-κ(3) o,n,o′]copper(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7472767/
https://www.ncbi.nlm.nih.gov/pubmed/32939315
http://dx.doi.org/10.1107/S2056989020011706
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