Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane

[Image: see text] Triflic acid-promoted 1-adamantylation and tert-butylation of pyrene at positions 2 and 2,7 along with the synthesis of compounds having one-, two-, and three-pyrenyl groups attached to the adamantane scaffold are disclosed. Fluorescent properties of these compounds and channeled c...

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Autores principales: Wrona-Piotrowicz, Anna, Makal, Anna, Zakrzewski, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7476028/
https://www.ncbi.nlm.nih.gov/pubmed/32786624
http://dx.doi.org/10.1021/acs.joc.0c01060
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author Wrona-Piotrowicz, Anna
Makal, Anna
Zakrzewski, Janusz
author_facet Wrona-Piotrowicz, Anna
Makal, Anna
Zakrzewski, Janusz
author_sort Wrona-Piotrowicz, Anna
collection PubMed
description [Image: see text] Triflic acid-promoted 1-adamantylation and tert-butylation of pyrene at positions 2 and 2,7 along with the synthesis of compounds having one-, two-, and three-pyrenyl groups attached to the adamantane scaffold are disclosed. Fluorescent properties of these compounds and channeled crystal structure of the 1,3,5-tris(pyren-2-yl)adamantane containing chloroform as a guest are also presented.
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spelling pubmed-74760282020-09-08 Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane Wrona-Piotrowicz, Anna Makal, Anna Zakrzewski, Janusz J Org Chem [Image: see text] Triflic acid-promoted 1-adamantylation and tert-butylation of pyrene at positions 2 and 2,7 along with the synthesis of compounds having one-, two-, and three-pyrenyl groups attached to the adamantane scaffold are disclosed. Fluorescent properties of these compounds and channeled crystal structure of the 1,3,5-tris(pyren-2-yl)adamantane containing chloroform as a guest are also presented. American Chemical Society 2020-08-07 2020-09-04 /pmc/articles/PMC7476028/ /pubmed/32786624 http://dx.doi.org/10.1021/acs.joc.0c01060 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Wrona-Piotrowicz, Anna
Makal, Anna
Zakrzewski, Janusz
Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane
title Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane
title_full Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane
title_fullStr Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane
title_full_unstemmed Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane
title_short Triflic Acid-Promoted Adamantylation and tert-Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane
title_sort triflic acid-promoted adamantylation and tert-butylation of pyrene: fluorescent properties of pyrene-decorated adamantanes and a channeled crystal structure of 1,3,5-tris(pyren-2-yl)adamantane
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7476028/
https://www.ncbi.nlm.nih.gov/pubmed/32786624
http://dx.doi.org/10.1021/acs.joc.0c01060
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