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Efficient [(NHC)Au(NTf(2))]-catalyzed hydrohydrazidation of terminal and internal alkynes
The efficient hydrohydrazidation of terminal (6a–r, 18 examples, 0.1–0.2 mol % [(NHC)Au(NTf(2))], T = 60 °C) and internal alkynes (7a–j, 10 examples, 0.2–0.5 mol % [(NHC)Au(NTf(2))], T = 60–80 °C) utilizing a complex with a sterically demanding bispentiptycenyl-substituted NHC ligand and the benign...
Autores principales: | Heidrich, Maximillian, Plenio, Herbert |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7476583/ https://www.ncbi.nlm.nih.gov/pubmed/32952724 http://dx.doi.org/10.3762/bjoc.16.175 |
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