Effect of Multidonor and Insertion Position of a Chromophore on the Photovoltaic Properties of Phenoxazine Dyes

[Image: see text] Research and development of new organic semiconductor materials can never be terminated because any structural fine-tuning may result in an important impact on its application performance, although the effect may be negative in many cases. Herein, we designed and synthesized a series of phenoxazine-based dyes, YH1, YH2, YH3, and YH4, whose absorption spectrum, electrochemical cyclic voltammetry, theoretical calculation, dye-sensitized solar cell photovoltaic characteristics, and electrochemical AC impedance are used to analyze the photophysical, electrochemical, and photovoltaic performance of the materials, aiming to study the effect of multidonor and adjustment of the chromophore insertion position on their photovoltaic performance. When donor triphenylamine is added at the end of YH1 and YH3, the absorption spectrum and photovoltaic performance of dyes YH2 and YH4 improved a little. The improvement is much greater when the chromophore (ethylenedioxy)thiophene in YH1 and YH2 is adjusted and inserted on the other side of phenoxazine and the energy conversion efficiencies (photon-to-current conversion efficiency) of the resulting dyes YH3 and YH4 reach 8.02 and 8.97%, respectively, which are 23 and 25% higher than those of YH1 and YH2, respectively. Although the improvement may be because of factors such as the dihedral angle, the result will undoubtedly provide some reference for the future study of the relationship between the structure and performance of organic dyes.