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Monitoring of Anthracene Using Nanoscale Au–Cu Bimetallic Alloy Nanoparticles Synthesized with Various Compositions
[Image: see text] Bimetallic alloy Au–Cu nanoparticles (Au–Cu alloy NPs) were synthesized using a chemical reduction method for sensing applications. Electronic absorption spectroscopy (UV–visible spectroscopy), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used for the confir...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482251/ https://www.ncbi.nlm.nih.gov/pubmed/32923808 http://dx.doi.org/10.1021/acsomega.0c03104 |
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author | Latif-ur-Rahman, Shah, Afzal Han, Changseok Jan, Abdul Khaliq |
author_facet | Latif-ur-Rahman, Shah, Afzal Han, Changseok Jan, Abdul Khaliq |
author_sort | Latif-ur-Rahman, |
collection | PubMed |
description | [Image: see text] Bimetallic alloy Au–Cu nanoparticles (Au–Cu alloy NPs) were synthesized using a chemical reduction method for sensing applications. Electronic absorption spectroscopy (UV–visible spectroscopy), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used for the confirmation and morphological studies of the synthesized nanoparticles. The composition of Au–Cu alloy NPs was studied by energy-dispersive spectroscopy (EDS). The high crystallinity of Au–Cu alloy NPs was demonstrated by XRD analysis. Both XRD and SEM analyses revealed that the nanoparticles’ size ranges from 15 to 25 nm. Pyrrole was polymerized into polypyrrole (PPy) over a neat and clean glassy carbon electrode (GCE) by potentiodynamic polymerization. The sensitivity of GCE was improved by modifying it into a composite electrode. The composite electrode was developed by coating GCE with an overoxidized PPy polymer followed by Au–Cu alloy NPs. The ratio of Au and Cu was carefully controlled. The composite electrode (PPyox/Au–Cu/GCE) successfully detected an environmental toxin anthracene with a detection limit of 0.15 μM, as evidenced by cyclic voltammetry (CV), square-wave voltammetry (SWV), and electrochemical impedance spectroscopy (EIS). |
format | Online Article Text |
id | pubmed-7482251 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-74822512020-09-11 Monitoring of Anthracene Using Nanoscale Au–Cu Bimetallic Alloy Nanoparticles Synthesized with Various Compositions Latif-ur-Rahman, Shah, Afzal Han, Changseok Jan, Abdul Khaliq ACS Omega [Image: see text] Bimetallic alloy Au–Cu nanoparticles (Au–Cu alloy NPs) were synthesized using a chemical reduction method for sensing applications. Electronic absorption spectroscopy (UV–visible spectroscopy), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used for the confirmation and morphological studies of the synthesized nanoparticles. The composition of Au–Cu alloy NPs was studied by energy-dispersive spectroscopy (EDS). The high crystallinity of Au–Cu alloy NPs was demonstrated by XRD analysis. Both XRD and SEM analyses revealed that the nanoparticles’ size ranges from 15 to 25 nm. Pyrrole was polymerized into polypyrrole (PPy) over a neat and clean glassy carbon electrode (GCE) by potentiodynamic polymerization. The sensitivity of GCE was improved by modifying it into a composite electrode. The composite electrode was developed by coating GCE with an overoxidized PPy polymer followed by Au–Cu alloy NPs. The ratio of Au and Cu was carefully controlled. The composite electrode (PPyox/Au–Cu/GCE) successfully detected an environmental toxin anthracene with a detection limit of 0.15 μM, as evidenced by cyclic voltammetry (CV), square-wave voltammetry (SWV), and electrochemical impedance spectroscopy (EIS). American Chemical Society 2020-08-24 /pmc/articles/PMC7482251/ /pubmed/32923808 http://dx.doi.org/10.1021/acsomega.0c03104 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Latif-ur-Rahman, Shah, Afzal Han, Changseok Jan, Abdul Khaliq Monitoring of Anthracene Using Nanoscale Au–Cu Bimetallic Alloy Nanoparticles Synthesized with Various Compositions |
title | Monitoring of Anthracene Using Nanoscale Au–Cu
Bimetallic Alloy Nanoparticles Synthesized with Various Compositions |
title_full | Monitoring of Anthracene Using Nanoscale Au–Cu
Bimetallic Alloy Nanoparticles Synthesized with Various Compositions |
title_fullStr | Monitoring of Anthracene Using Nanoscale Au–Cu
Bimetallic Alloy Nanoparticles Synthesized with Various Compositions |
title_full_unstemmed | Monitoring of Anthracene Using Nanoscale Au–Cu
Bimetallic Alloy Nanoparticles Synthesized with Various Compositions |
title_short | Monitoring of Anthracene Using Nanoscale Au–Cu
Bimetallic Alloy Nanoparticles Synthesized with Various Compositions |
title_sort | monitoring of anthracene using nanoscale au–cu
bimetallic alloy nanoparticles synthesized with various compositions |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482251/ https://www.ncbi.nlm.nih.gov/pubmed/32923808 http://dx.doi.org/10.1021/acsomega.0c03104 |
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