Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene

[Image: see text] The products of the solid-state reactions between potassium metal and tetracene (K:Tetracene, 1:1, 1.5:1, and 2:1) are fully structurally characterized. Synchrotron X-ray powder diffraction shows that only K(2)Tetracene forms under the reaction conditions studied, with unreacted te...

Descripción completa

Detalles Bibliográficos
Autores principales: Hiley, Craig I., Inglis, Kenneth K., Zanella, Marco, Zhang, Jiliang, Manning, Troy D., Dyer, Matthew S., Knaflič, Tilen, Arčon, Denis, Blanc, Frédéric, Prassides, Kosmas, Rosseinsky, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482393/
https://www.ncbi.nlm.nih.gov/pubmed/32805995
http://dx.doi.org/10.1021/acs.inorgchem.0c01635
_version_ 1783580781590872064
author Hiley, Craig I.
Inglis, Kenneth K.
Zanella, Marco
Zhang, Jiliang
Manning, Troy D.
Dyer, Matthew S.
Knaflič, Tilen
Arčon, Denis
Blanc, Frédéric
Prassides, Kosmas
Rosseinsky, Matthew J.
author_facet Hiley, Craig I.
Inglis, Kenneth K.
Zanella, Marco
Zhang, Jiliang
Manning, Troy D.
Dyer, Matthew S.
Knaflič, Tilen
Arčon, Denis
Blanc, Frédéric
Prassides, Kosmas
Rosseinsky, Matthew J.
author_sort Hiley, Craig I.
collection PubMed
description [Image: see text] The products of the solid-state reactions between potassium metal and tetracene (K:Tetracene, 1:1, 1.5:1, and 2:1) are fully structurally characterized. Synchrotron X-ray powder diffraction shows that only K(2)Tetracene forms under the reaction conditions studied, with unreacted tetracene always present for x < 2. Diffraction and (13)C MAS NMR show that K(2)Tetracene has a crystal structure that is analogous to that of K(2)Pentacene, but with the cations ordered on two sites because of the influence of the length of the hydrocarbon on possible cation positions. K(2)Tetracene is a nonmagnetic insulator, thus further questioning the nature of reported superconductivity in this class of materials.
format Online
Article
Text
id pubmed-7482393
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-74823932020-09-11 Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene Hiley, Craig I. Inglis, Kenneth K. Zanella, Marco Zhang, Jiliang Manning, Troy D. Dyer, Matthew S. Knaflič, Tilen Arčon, Denis Blanc, Frédéric Prassides, Kosmas Rosseinsky, Matthew J. Inorg Chem [Image: see text] The products of the solid-state reactions between potassium metal and tetracene (K:Tetracene, 1:1, 1.5:1, and 2:1) are fully structurally characterized. Synchrotron X-ray powder diffraction shows that only K(2)Tetracene forms under the reaction conditions studied, with unreacted tetracene always present for x < 2. Diffraction and (13)C MAS NMR show that K(2)Tetracene has a crystal structure that is analogous to that of K(2)Pentacene, but with the cations ordered on two sites because of the influence of the length of the hydrocarbon on possible cation positions. K(2)Tetracene is a nonmagnetic insulator, thus further questioning the nature of reported superconductivity in this class of materials. American Chemical Society 2020-08-11 2020-09-08 /pmc/articles/PMC7482393/ /pubmed/32805995 http://dx.doi.org/10.1021/acs.inorgchem.0c01635 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Hiley, Craig I.
Inglis, Kenneth K.
Zanella, Marco
Zhang, Jiliang
Manning, Troy D.
Dyer, Matthew S.
Knaflič, Tilen
Arčon, Denis
Blanc, Frédéric
Prassides, Kosmas
Rosseinsky, Matthew J.
Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene
title Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene
title_full Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene
title_fullStr Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene
title_full_unstemmed Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene
title_short Crystal Structure and Stoichiometric Composition of Potassium-Intercalated Tetracene
title_sort crystal structure and stoichiometric composition of potassium-intercalated tetracene
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482393/
https://www.ncbi.nlm.nih.gov/pubmed/32805995
http://dx.doi.org/10.1021/acs.inorgchem.0c01635
work_keys_str_mv AT hileycraigi crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT ingliskennethk crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT zanellamarco crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT zhangjiliang crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT manningtroyd crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT dyermatthews crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT knaflictilen crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT arcondenis crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT blancfrederic crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT prassideskosmas crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene
AT rosseinskymatthewj crystalstructureandstoichiometriccompositionofpotassiumintercalatedtetracene

Ejemplares similares