Cargando…

Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers

[Image: see text] Six polymers were prepared with 4,4′,4″-(1,3,5-triazine-2,4,6-triyl)triphenylamine as the amine unit, and six different aldehyde units as substrates. The effects of the number of thiophene and benzene rings on the degradation of tetracycline (TC) in water were studied using polymer...

Descripción completa

Detalles Bibliográficos
Autores principales: Du, Wanjun, Ni, Cailing, Zhou, Yubing, Qin, Yuancheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482411/
https://www.ncbi.nlm.nih.gov/pubmed/32923827
http://dx.doi.org/10.1021/acsomega.0c03490
_version_ 1783580785116184576
author Du, Wanjun
Ni, Cailing
Zhou, Yubing
Qin, Yuancheng
author_facet Du, Wanjun
Ni, Cailing
Zhou, Yubing
Qin, Yuancheng
author_sort Du, Wanjun
collection PubMed
description [Image: see text] Six polymers were prepared with 4,4′,4″-(1,3,5-triazine-2,4,6-triyl)triphenylamine as the amine unit, and six different aldehyde units as substrates. The effects of the number of thiophene and benzene rings on the degradation of tetracycline (TC) in water were studied using polymer photocatalysts, and the reaction mechanism was discussed. The results indicate that ThTA-3 containing three thiophene group monomers and BATA-1 with one benzene ring unit monomer have higher absorption and utilization of visible light. In addition, ThTA-3 and BATA-1 have stronger charge separation and transfer capabilities and better morphology and thermal stability.
format Online
Article
Text
id pubmed-7482411
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-74824112020-09-11 Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers Du, Wanjun Ni, Cailing Zhou, Yubing Qin, Yuancheng ACS Omega [Image: see text] Six polymers were prepared with 4,4′,4″-(1,3,5-triazine-2,4,6-triyl)triphenylamine as the amine unit, and six different aldehyde units as substrates. The effects of the number of thiophene and benzene rings on the degradation of tetracycline (TC) in water were studied using polymer photocatalysts, and the reaction mechanism was discussed. The results indicate that ThTA-3 containing three thiophene group monomers and BATA-1 with one benzene ring unit monomer have higher absorption and utilization of visible light. In addition, ThTA-3 and BATA-1 have stronger charge separation and transfer capabilities and better morphology and thermal stability. American Chemical Society 2020-08-27 /pmc/articles/PMC7482411/ /pubmed/32923827 http://dx.doi.org/10.1021/acsomega.0c03490 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Du, Wanjun
Ni, Cailing
Zhou, Yubing
Qin, Yuancheng
Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers
title Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers
title_full Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers
title_fullStr Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers
title_full_unstemmed Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers
title_short Effects of Thiophene and Benzene Ring Accumulation on the Photocatalytic Performance of Polymers
title_sort effects of thiophene and benzene ring accumulation on the photocatalytic performance of polymers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482411/
https://www.ncbi.nlm.nih.gov/pubmed/32923827
http://dx.doi.org/10.1021/acsomega.0c03490
work_keys_str_mv AT duwanjun effectsofthiopheneandbenzeneringaccumulationonthephotocatalyticperformanceofpolymers
AT nicailing effectsofthiopheneandbenzeneringaccumulationonthephotocatalyticperformanceofpolymers
AT zhouyubing effectsofthiopheneandbenzeneringaccumulationonthephotocatalyticperformanceofpolymers
AT qinyuancheng effectsofthiopheneandbenzeneringaccumulationonthephotocatalyticperformanceofpolymers