Impact of fluorination on interface energetics and growth of pentacene on Ag(111)

We studied the structural and electronic properties of 2,3,9,10-tetrafluoropentacene (F4PEN) on Ag(111) via X-ray standing waves (XSW), low-energy electron diffraction (LEED) as well as ultraviolet and X-ray photoelectron spectroscopy (UPS and XPS). XSW revealed that the adsorption distances of F4PE...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Qi, Chen, Meng-Ting, Franco-Cañellas, Antoni, Shen, Bin, Geiger, Thomas, F. Bettinger, Holger, Schreiber, Frank, Salzmann, Ingo, Gerlach, Alexander, Duhm, Steffen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7492695/
https://www.ncbi.nlm.nih.gov/pubmed/32974114
http://dx.doi.org/10.3762/bjnano.11.120
Descripción
Sumario:We studied the structural and electronic properties of 2,3,9,10-tetrafluoropentacene (F4PEN) on Ag(111) via X-ray standing waves (XSW), low-energy electron diffraction (LEED) as well as ultraviolet and X-ray photoelectron spectroscopy (UPS and XPS). XSW revealed that the adsorption distances of F4PEN in (sub)monolayers on Ag(111) were 3.00 Å for carbon atoms and 3.05 Å for fluorine atoms. The F4PEN monolayer was essentially lying on Ag(111), and multilayers adopted π-stacking. Our study shed light not only on the F4PEN–Ag(111) interface but also on the fundamental adsorption behavior of fluorinated pentacene derivatives on metals in the context of interface energetics and growth mode.

Ejemplares similares