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A Tandem Iridium-Catalyzed “Chain-Walking”/Cope Rearrangement Sequence
[Image: see text] An iridium-catalyzed tandem olefin migration/Cope rearrangement of alkenyl ω-ene cyclopropanes is reported. By this means, a variety of complex annulenes are obtained as single diastereomers starting from cyclopropyl ester derived from simple 1,ω-dienes and alkenyldiazo compounds....
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7493306/ https://www.ncbi.nlm.nih.gov/pubmed/32953237 http://dx.doi.org/10.1021/acscatal.9b00118 |