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Addition of alkynes and osmium carbynes towards functionalized d(π)–p(π) conjugated systems

The metal-carbon triple bonds and carbon-carbon triple bonds are both highly unsaturated bonds. As a result, their reactions tend to afford cycloaddition intermediates or products. Herein, we report a reaction of M≡C and C≡C bonds that affords acyclic addition products. These newly discovered reacti...

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Detalles Bibliográficos
Autores principales:	Chen, Shiyan, Liu, Longzhu, Gao, Xiang, Hua, Yuhui, Peng, Lixia, Zhang, Ying, Yang, Liulin, Tan, Yuanzhi, He, Feng, Xia, Haiping
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7495419/ https://www.ncbi.nlm.nih.gov/pubmed/32938934 http://dx.doi.org/10.1038/s41467-020-18498-2

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