Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS

[Image: see text] To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography–mass spectrometry (LC–MS) an...

Descripción completa

Detalles Bibliográficos
Autores principales: Shi, Ning, Liu, Qiying, Liu, Ying, Chen, Lijun, Zhang, Hongyan, Huang, Hongsheng, Ma, Longlong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496007/
https://www.ncbi.nlm.nih.gov/pubmed/32954183
http://dx.doi.org/10.1021/acsomega.0c03169
_version_ 1783583002497908736
author Shi, Ning
Liu, Qiying
Liu, Ying
Chen, Lijun
Zhang, Hongyan
Huang, Hongsheng
Ma, Longlong
author_facet Shi, Ning
Liu, Qiying
Liu, Ying
Chen, Lijun
Zhang, Hongyan
Huang, Hongsheng
Ma, Longlong
author_sort Shi, Ning
collection PubMed
description [Image: see text] To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography–mass spectrometry (LC–MS) and LC–MS/MS. Multiple carbocyclic compounds containing hydroxy group and carbonyl group were detected, with a molecular mass in the range of 154–272 Da and carbon chain of the length 8–15. The formation of these soluble carbocyclic compounds was proposed to involve hydrolytic ring-opening of the furanic ring, intermolecular aldol condensation, intramolecular aldol condensation, and C–C cleavage reaction. The C–C cleavage reaction was proposed to occur on the dicarbonyl structure of the formed primary polymers.
format Online
Article
Text
id pubmed-7496007
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-74960072020-09-18 Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS Shi, Ning Liu, Qiying Liu, Ying Chen, Lijun Zhang, Hongyan Huang, Hongsheng Ma, Longlong ACS Omega [Image: see text] To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography–mass spectrometry (LC–MS) and LC–MS/MS. Multiple carbocyclic compounds containing hydroxy group and carbonyl group were detected, with a molecular mass in the range of 154–272 Da and carbon chain of the length 8–15. The formation of these soluble carbocyclic compounds was proposed to involve hydrolytic ring-opening of the furanic ring, intermolecular aldol condensation, intramolecular aldol condensation, and C–C cleavage reaction. The C–C cleavage reaction was proposed to occur on the dicarbonyl structure of the formed primary polymers. American Chemical Society 2020-09-01 /pmc/articles/PMC7496007/ /pubmed/32954183 http://dx.doi.org/10.1021/acsomega.0c03169 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Shi, Ning
Liu, Qiying
Liu, Ying
Chen, Lijun
Zhang, Hongyan
Huang, Hongsheng
Ma, Longlong
Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS
title Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS
title_full Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS
title_fullStr Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS
title_full_unstemmed Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS
title_short Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC–MS/MS
title_sort characterization of the soluble products formed during the hydrothermal conversion of biomass-derived furanic compounds by using lc–ms/ms
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496007/
https://www.ncbi.nlm.nih.gov/pubmed/32954183
http://dx.doi.org/10.1021/acsomega.0c03169
work_keys_str_mv AT shining characterizationofthesolubleproductsformedduringthehydrothermalconversionofbiomassderivedfuraniccompoundsbyusinglcmsms
AT liuqiying characterizationofthesolubleproductsformedduringthehydrothermalconversionofbiomassderivedfuraniccompoundsbyusinglcmsms
AT liuying characterizationofthesolubleproductsformedduringthehydrothermalconversionofbiomassderivedfuraniccompoundsbyusinglcmsms
AT chenlijun characterizationofthesolubleproductsformedduringthehydrothermalconversionofbiomassderivedfuraniccompoundsbyusinglcmsms
AT zhanghongyan characterizationofthesolubleproductsformedduringthehydrothermalconversionofbiomassderivedfuraniccompoundsbyusinglcmsms
AT huanghongsheng characterizationofthesolubleproductsformedduringthehydrothermalconversionofbiomassderivedfuraniccompoundsbyusinglcmsms
AT malonglong characterizationofthesolubleproductsformedduringthehydrothermalconversionofbiomassderivedfuraniccompoundsbyusinglcmsms

Ejemplares similares