Cargando…

Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles

Various polyimides and polyamides have recently been prepared via hydrothermal synthesis in nothing but H(2)O under high‐pressure and high‐temperature conditions. However, none of the prepared polymers feature a truly conjugated polymer backbone. Here, we report on an expansion of the synthetic scop...

Descripción completa

Detalles Bibliográficos
Autores principales: Taublaender, M. Josef, Mezzavilla, Stefano, Thiele, Sophia, Glöcklhofer, Florian, Unterlass, Miriam M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496105/
https://www.ncbi.nlm.nih.gov/pubmed/32255546
http://dx.doi.org/10.1002/anie.202000367
_version_ 1783583023964356608
author Taublaender, M. Josef
Mezzavilla, Stefano
Thiele, Sophia
Glöcklhofer, Florian
Unterlass, Miriam M.
author_facet Taublaender, M. Josef
Mezzavilla, Stefano
Thiele, Sophia
Glöcklhofer, Florian
Unterlass, Miriam M.
author_sort Taublaender, M. Josef
collection PubMed
description Various polyimides and polyamides have recently been prepared via hydrothermal synthesis in nothing but H(2)O under high‐pressure and high‐temperature conditions. However, none of the prepared polymers feature a truly conjugated polymer backbone. Here, we report on an expansion of the synthetic scope of this straightforward and inherently environmentally friendly polymerization technique to the generation of conjugated polymers. Selected representatives of two different polymer classes, pyrrone polymers and polybenzimidazoles, were generated hydrothermally. We present a mechanistic discussion of the polymer formation process as well as an electrochemical characterization of the most promising product.
format Online
Article
Text
id pubmed-7496105
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-74961052020-09-25 Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles Taublaender, M. Josef Mezzavilla, Stefano Thiele, Sophia Glöcklhofer, Florian Unterlass, Miriam M. Angew Chem Int Ed Engl Research Articles Various polyimides and polyamides have recently been prepared via hydrothermal synthesis in nothing but H(2)O under high‐pressure and high‐temperature conditions. However, none of the prepared polymers feature a truly conjugated polymer backbone. Here, we report on an expansion of the synthetic scope of this straightforward and inherently environmentally friendly polymerization technique to the generation of conjugated polymers. Selected representatives of two different polymer classes, pyrrone polymers and polybenzimidazoles, were generated hydrothermally. We present a mechanistic discussion of the polymer formation process as well as an electrochemical characterization of the most promising product. John Wiley and Sons Inc. 2020-05-11 2020-08-24 /pmc/articles/PMC7496105/ /pubmed/32255546 http://dx.doi.org/10.1002/anie.202000367 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Taublaender, M. Josef
Mezzavilla, Stefano
Thiele, Sophia
Glöcklhofer, Florian
Unterlass, Miriam M.
Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles
title Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles
title_full Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles
title_fullStr Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles
title_full_unstemmed Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles
title_short Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles
title_sort hydrothermal generation of conjugated polymers using the example of pyrrone polymers and polybenzimidazoles
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496105/
https://www.ncbi.nlm.nih.gov/pubmed/32255546
http://dx.doi.org/10.1002/anie.202000367
work_keys_str_mv AT taublaendermjosef hydrothermalgenerationofconjugatedpolymersusingtheexampleofpyrronepolymersandpolybenzimidazoles
AT mezzavillastefano hydrothermalgenerationofconjugatedpolymersusingtheexampleofpyrronepolymersandpolybenzimidazoles
AT thielesophia hydrothermalgenerationofconjugatedpolymersusingtheexampleofpyrronepolymersandpolybenzimidazoles
AT glocklhoferflorian hydrothermalgenerationofconjugatedpolymersusingtheexampleofpyrronepolymersandpolybenzimidazoles
AT unterlassmiriamm hydrothermalgenerationofconjugatedpolymersusingtheexampleofpyrronepolymersandpolybenzimidazoles