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Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes
The reaction of zerovalent nickel compounds with white phosphorus (P(4)) is a barely explored route to binary nickel phosphide clusters. Here, we show that coordinatively and electronically unsaturated N‐heterocyclic carbene (NHC) nickel(0) complexes afford unusual cluster compounds with P(1), P(3),...
Autores principales: | Hierlmeier, Gabriele, Coburger, Peter, van Leest, Nicolaas P., de Bruin, Bas, Wolf, Robert |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496536/ https://www.ncbi.nlm.nih.gov/pubmed/32348622 http://dx.doi.org/10.1002/anie.202004020 |
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