A Hexabenzocoronene‐Based Helical Nanographene

A synthetic route towards a novel hexabenzocoronene‐based helical nanographene motif was developed. A hexaphenylbenzene precursor was therefore designed, which cannot undergo, due to steric restrictions, a complete planarization reaction. This precursor was transformed under oxidative cyclodehydroge...

Descripción completa

Detalles Bibliográficos
Autores principales: Martin, Max M., Hampel, Frank, Jux, Norbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496628/
https://www.ncbi.nlm.nih.gov/pubmed/32338388
http://dx.doi.org/10.1002/chem.202001471
_version_ 1783583140212637696
author Martin, Max M.
Hampel, Frank
Jux, Norbert
author_facet Martin, Max M.
Hampel, Frank
Jux, Norbert
author_sort Martin, Max M.
collection PubMed
description A synthetic route towards a novel hexabenzocoronene‐based helical nanographene motif was developed. A hexaphenylbenzene precursor was therefore designed, which cannot undergo, due to steric restrictions, a complete planarization reaction. This precursor was transformed under oxidative cyclodehydrogenation conditions to a π‐extended [5]helicene, which was fully characterized including X‐ray diffraction analysis.
format Online
Article
Text
id pubmed-7496628
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-74966282020-09-25 A Hexabenzocoronene‐Based Helical Nanographene Martin, Max M. Hampel, Frank Jux, Norbert Chemistry Communications A synthetic route towards a novel hexabenzocoronene‐based helical nanographene motif was developed. A hexaphenylbenzene precursor was therefore designed, which cannot undergo, due to steric restrictions, a complete planarization reaction. This precursor was transformed under oxidative cyclodehydrogenation conditions to a π‐extended [5]helicene, which was fully characterized including X‐ray diffraction analysis. John Wiley and Sons Inc. 2020-07-10 2020-08-12 /pmc/articles/PMC7496628/ /pubmed/32338388 http://dx.doi.org/10.1002/chem.202001471 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Martin, Max M.
Hampel, Frank
Jux, Norbert
A Hexabenzocoronene‐Based Helical Nanographene
title A Hexabenzocoronene‐Based Helical Nanographene
title_full A Hexabenzocoronene‐Based Helical Nanographene
title_fullStr A Hexabenzocoronene‐Based Helical Nanographene
title_full_unstemmed A Hexabenzocoronene‐Based Helical Nanographene
title_short A Hexabenzocoronene‐Based Helical Nanographene
title_sort hexabenzocoronene‐based helical nanographene
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496628/
https://www.ncbi.nlm.nih.gov/pubmed/32338388
http://dx.doi.org/10.1002/chem.202001471
work_keys_str_mv AT martinmaxm ahexabenzocoronenebasedhelicalnanographene
AT hampelfrank ahexabenzocoronenebasedhelicalnanographene
AT juxnorbert ahexabenzocoronenebasedhelicalnanographene
AT martinmaxm hexabenzocoronenebasedhelicalnanographene
AT hampelfrank hexabenzocoronenebasedhelicalnanographene
AT juxnorbert hexabenzocoronenebasedhelicalnanographene

Ejemplares similares