Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines

A new series of 2,4,6‐triaryl‐λ(5)‐phosphinines have been synthesized that contain different substituents both on the carbon backbone and the phosphorus atom of the six‐membered heterocycle. Their optical and redox properties were studied in detail, supported by in‐depth theoretical calculations. Th...

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Autores principales: Pfeifer, Gregor, Chahdoura, Faouzi, Papke, Martin, Weber, Manuela, Szűcs, Rózsa, Geffroy, Bernard, Tondelier, Denis, Nyulászi, László, Hissler, Muriel, Müller, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496645/
https://www.ncbi.nlm.nih.gov/pubmed/32092780
http://dx.doi.org/10.1002/chem.202000932
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author Pfeifer, Gregor
Chahdoura, Faouzi
Papke, Martin
Weber, Manuela
Szűcs, Rózsa
Geffroy, Bernard
Tondelier, Denis
Nyulászi, László
Hissler, Muriel
Müller, Christian
author_facet Pfeifer, Gregor
Chahdoura, Faouzi
Papke, Martin
Weber, Manuela
Szűcs, Rózsa
Geffroy, Bernard
Tondelier, Denis
Nyulászi, László
Hissler, Muriel
Müller, Christian
author_sort Pfeifer, Gregor
collection PubMed
description A new series of 2,4,6‐triaryl‐λ(5)‐phosphinines have been synthesized that contain different substituents both on the carbon backbone and the phosphorus atom of the six‐membered heterocycle. Their optical and redox properties were studied in detail, supported by in‐depth theoretical calculations. The modularity of the synthetic strategy allowed the establishment of structure–property relationships for this class of compounds and an OLED based on a blue phosphinine emitter could be developed for the first time.
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spelling pubmed-74966452020-09-25 Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines Pfeifer, Gregor Chahdoura, Faouzi Papke, Martin Weber, Manuela Szűcs, Rózsa Geffroy, Bernard Tondelier, Denis Nyulászi, László Hissler, Muriel Müller, Christian Chemistry Full Papers A new series of 2,4,6‐triaryl‐λ(5)‐phosphinines have been synthesized that contain different substituents both on the carbon backbone and the phosphorus atom of the six‐membered heterocycle. Their optical and redox properties were studied in detail, supported by in‐depth theoretical calculations. The modularity of the synthetic strategy allowed the establishment of structure–property relationships for this class of compounds and an OLED based on a blue phosphinine emitter could be developed for the first time. John Wiley and Sons Inc. 2020-08-06 2020-08-17 /pmc/articles/PMC7496645/ /pubmed/32092780 http://dx.doi.org/10.1002/chem.202000932 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Full Papers
Pfeifer, Gregor
Chahdoura, Faouzi
Papke, Martin
Weber, Manuela
Szűcs, Rózsa
Geffroy, Bernard
Tondelier, Denis
Nyulászi, László
Hissler, Muriel
Müller, Christian
Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines
title Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines
title_full Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines
title_fullStr Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines
title_full_unstemmed Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines
title_short Synthesis, Electronic Properties and OLED Devices of Chromophores Based on λ(5)‐Phosphinines
title_sort synthesis, electronic properties and oled devices of chromophores based on λ(5)‐phosphinines
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496645/
https://www.ncbi.nlm.nih.gov/pubmed/32092780
http://dx.doi.org/10.1002/chem.202000932
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