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2,7,11,16‐Tetra‐tert‐Butyl Tetraindenopyrene Revisited by an “Inverse” Synthetic Approach

A new synthetic route to tetraindenopyrene (TIP)—a bowl‐shaped cut‐out structure of C(70)—is reported. The key step in this approach is a fourfold palladium‐catalyzed C−H activation that increases the yield more than 50 times in comparison to the approach originally described by Scott and co‐workers...

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Detalles Bibliográficos
Autores principales: Elbert, Sven M., Haidisch, Anika, Kirschbaum, Tobias, Rominger, Frank, Zschieschang, Ute, Klauk, Hagen, Mastalerz, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496754/
https://www.ncbi.nlm.nih.gov/pubmed/32314830
http://dx.doi.org/10.1002/chem.202001555

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