Reversible N‐Heterocyclic Carbene‐Induced α‐H Abstraction in Tungsten(VI) Imido Dialkyl Dialkoxide Complexes

The first reversible N‐heterocyclic carbene (NHC) induced α‐H abstraction in tungsten(VI) imido‐dialkyl dialkoxide complexes is reported. Treatment of W(NAr)(CH(2)Ph)(2)(OtBu)(2) (Ar=2,6‐dichlorophenyl, 2,6‐dimethylphenyl, 2,6‐diisopropylphenyl) with different NHCs leads to the formation of complexe...

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Detalles Bibliográficos
Autores principales: Musso, Janis V., Benedikter, Mathis J., Wang, Dongren, Frey, Wolfgang, Altmann, Hagen J., Buchmeiser, Michael R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496809/
https://www.ncbi.nlm.nih.gov/pubmed/32202338
http://dx.doi.org/10.1002/chem.202000840

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496809/
https://www.ncbi.nlm.nih.gov/pubmed/32202338
http://dx.doi.org/10.1002/chem.202000840

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