Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions

Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m‐terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9‐phospha‐ and 9‐arsena‐fluorenium ions.

Detalles Bibliográficos
Autores principales: Olaru, Marian, Duvinage, Daniel, Naß, Yannik, Malaspina, Lorraine A., Mebs, Stefan, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496934/
https://www.ncbi.nlm.nih.gov/pubmed/32460394
http://dx.doi.org/10.1002/anie.202006728
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author Olaru, Marian
Duvinage, Daniel
Naß, Yannik
Malaspina, Lorraine A.
Mebs, Stefan
Beckmann, Jens
author_facet Olaru, Marian
Duvinage, Daniel
Naß, Yannik
Malaspina, Lorraine A.
Mebs, Stefan
Beckmann, Jens
author_sort Olaru, Marian
collection PubMed
description Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m‐terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9‐phospha‐ and 9‐arsena‐fluorenium ions.
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spelling pubmed-74969342020-09-25 Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions Olaru, Marian Duvinage, Daniel Naß, Yannik Malaspina, Lorraine A. Mebs, Stefan Beckmann, Jens Angew Chem Int Ed Engl Communications Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m‐terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9‐phospha‐ and 9‐arsena‐fluorenium ions. John Wiley and Sons Inc. 2020-07-06 2020-08-17 /pmc/articles/PMC7496934/ /pubmed/32460394 http://dx.doi.org/10.1002/anie.202006728 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Olaru, Marian
Duvinage, Daniel
Naß, Yannik
Malaspina, Lorraine A.
Mebs, Stefan
Beckmann, Jens
Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions
title Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions
title_full Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions
title_fullStr Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions
title_full_unstemmed Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions
title_short Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions
title_sort intramolecular reaction of transient phosphenium and arsenium ions giving rise to isolable 9‐phospha‐ and 9‐arsena‐fluorenium ions
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496934/
https://www.ncbi.nlm.nih.gov/pubmed/32460394
http://dx.doi.org/10.1002/anie.202006728
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