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Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions

Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m‐terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9‐phospha‐ and 9‐arsena‐fluorenium ions.

Detalles Bibliográficos
Autores principales: Olaru, Marian, Duvinage, Daniel, Naß, Yannik, Malaspina, Lorraine A., Mebs, Stefan, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496934/
https://www.ncbi.nlm.nih.gov/pubmed/32460394
http://dx.doi.org/10.1002/anie.202006728