Electrophilic Vinylation of Thiols under Mild and Transition Metal‐Free Conditions

The iodine(III) reagents vinylbenziodoxolones (VBX) were employed to vinylate a series of aliphatic and aromatic thiols, providing E‐alkenyl sulfides with complete chemo‐ and regioselectivity, as well as excellent stereoselectivity. The methodology displays high functional group tolerance and procee...

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Detalles Bibliográficos
Autores principales: Castoldi, Laura, Di Tommaso, Ester Maria, Reitti, Marcus, Gräfen, Barbara, Olofsson, Berit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497129/
https://www.ncbi.nlm.nih.gov/pubmed/32395880
http://dx.doi.org/10.1002/anie.202002936

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497129/
https://www.ncbi.nlm.nih.gov/pubmed/32395880
http://dx.doi.org/10.1002/anie.202002936

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