Cargando…
N‐Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence
A study on the reactivity of the N‐heterocyclic silylene Dipp(2)NHSi (1,3‐bis(diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐en‐2‐yliden) with the transition metal complexes [Ni(CO)(4)], [M(CO)(6)] (M=Cr, Mo, W), [Mn(CO)(5)(Br)] and [(η (5)‐C(5)H(5))Fe(CO)(2)(I)] is reported. We demonstrate that N‐h...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497151/ https://www.ncbi.nlm.nih.gov/pubmed/32233000 http://dx.doi.org/10.1002/chem.202001062 |