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Enantiomerically Pure Tetravalent Neptunium Amidinates: Synthesis and Characterization

The synthesis of a tetravalent neptunium amidinate [NpCl((S)‐PEBA)(3)] (1) ((S)‐PEBA=(S,S)‐N,N′‐bis‐(1‐phenylethyl)‐benzamidinate) is reported. This complex represents the first structurally characterized enantiopure transuranic compound. Reactivity studies with halide/pseudohalides yielding [NpX((S...

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Detalles Bibliográficos
Autores principales:	Fichter, Sebastian, Kaufmann, Sebastian, Kaden, Peter, Brunner, Tobias S., Stumpf, Thorsten, Roesky, Peter W., März, Juliane
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497184/ https://www.ncbi.nlm.nih.gov/pubmed/32347986 http://dx.doi.org/10.1002/chem.202001865

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