Cargando…
A Predictive Model Towards Site‐Selective Metalations of Functionalized Heterocycles, Arenes, Olefins, and Alkanes using TMPZnCl⋅LiCl
The development of a predictive model towards site‐selective deprotometalation reactions using TMPZnCl⋅LiCl is reported (TMP=2,2,6,6‐tetramethylpiperidinyl). The pK (a) values of functionalized N‐, S‐, and O‐heterocycles, arenes, alkenes, or alkanes were calculated and compared to the experimental d...
Autores principales: | Balkenhohl, Moritz, Jangra, Harish, Makarov, Ilya S., Yang, Shu‐Mei, Zipse, Hendrik, Knochel, Paul |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497272/ https://www.ncbi.nlm.nih.gov/pubmed/32400069 http://dx.doi.org/10.1002/anie.202005372 |
Ejemplares similares
-
Preparation of Polyfunctional Biaryl Derivatives by Cyclolanthanation of 2‐Bromobiaryls and Heterocyclic Analogues Using nBu(2)LaCl⋅4 LiCl
por: Wei, Baosheng, et al.
Publicado: (2019) -
Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX⋅LiX (X=Cl, Br)
por: Kremsmair, Alexander, et al.
Publicado: (2022) -
Presence of Li Clusters in Molten LiCl-Li
por: Merwin, Augustus, et al.
Publicado: (2016) -
Glass Polymorphism
in Hyperquenched Aqueous LiCl
Solutions
por: Giebelmann, Johannes, et al.
Publicado: (2023) -
Hydration of LiOH and LiCl—Near-Infrared Spectroscopic
Analysis
por: Takeuchi, Masato, et al.
Publicado: (2021)