Impact of Excited-State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes

[Image: see text] Benzene exhibits a rich photochemistry which can provide access to complex molecular scaffolds that are difficult to access with reactions in the electronic ground state. While benzene is aromatic in its ground state, it is antiaromatic in its lowest ππ* excited states. Herein, we...

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Detalles Bibliográficos
Autores principales: Slanina, Tomáš, Ayub, Rabia, Toldo, Josene, Sundell, Johan, Rabten, Wangchuk, Nicaso, Marco, Alabugin, Igor, Fdez. Galván, Ignacio, Gupta, Arvind K., Lindh, Roland, Orthaber, Andreas, Lewis, Richard J., Grönberg, Gunnar, Bergman, Joakim, Ottosson, Henrik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497645/
https://www.ncbi.nlm.nih.gov/pubmed/32456426
http://dx.doi.org/10.1021/jacs.9b13769

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