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Stereospecific Isomerization of Allylic Halides via Ion Pairs with Induced Noncovalent Chirality

[Image: see text] A regioselective protocol for the synthesis of substituted allylic chlorides, bromides, and fluorides has been established. Remarkably, the method can be applied to the enantioselective synthesis of challenging chiral allylic chlorides. When the allylic halides are treated with the...

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Detalles Bibliográficos
Autores principales: Martinez-Erro, Samuel, García-Vázquez, Víctor, Sanz-Marco, Amparo, Martín-Matute, Belén
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497663/
https://www.ncbi.nlm.nih.gov/pubmed/32383608
http://dx.doi.org/10.1021/acs.orglett.0c01200