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Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes
In order to synthesize new iron (II) complexes of 1,5-diaza-3,7-diphosphacyclooctanes with a wider variety of the substituents on ligands heteroatoms (including functionalized ones, namely, pyridyl groups) and co-ligands, it was found that these ligands with relatively small phenyl, benzyl, and pyri...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7503606/ https://www.ncbi.nlm.nih.gov/pubmed/32825126 http://dx.doi.org/10.3390/molecules25173775 |
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author | Spiridonova, Yulia S. Nikolaeva, Yulia A. Balueva, Anna S. Musina, Elvira I. Litvinov, Igor A. Strelnik, Igor D. Khrizanforova, Vera V. Budnikova, Yulia G. Karasik, Andrey A. |
author_facet | Spiridonova, Yulia S. Nikolaeva, Yulia A. Balueva, Anna S. Musina, Elvira I. Litvinov, Igor A. Strelnik, Igor D. Khrizanforova, Vera V. Budnikova, Yulia G. Karasik, Andrey A. |
author_sort | Spiridonova, Yulia S. |
collection | PubMed |
description | In order to synthesize new iron (II) complexes of 1,5-diaza-3,7-diphosphacyclooctanes with a wider variety of the substituents on ligands heteroatoms (including functionalized ones, namely, pyridyl groups) and co-ligands, it was found that these ligands with relatively small phenyl, benzyl, and pyridin-2-yl substituents on phosphorus atoms in acetonitrile formed bis-P,P-chelate cis-complexes [L(2)Fe(CH(3)CN)(2)](2+) (BF(4))(2)(−), whereas P-mesityl-substituted ligand formed only monoligand P,P-complex [LFe(CH(3)CN)(4)](2+) (BF(4))(2)(−). 3,7-dibenzyl-1,5-di(1′-(R)-phenylethyl)-1,5-diaza-3,7-diphosphacyclooctane reacted with hexahydrate of iron (II) tetrafluoroborate in acetone to give an unusual bis-ligand cationic complex of the composition [L(2)Fe(BF(4))](+) BF(4)(−), where two fluorine atoms of the tetrafluoroborate unit occupied two pseudo-equatorial positions at roughly octahedral iron ion, according to X-ray diffraction data. 1,5-diaza-3,7-diphosphacyclooctanes replaced tetrahydrofurane and one of the carbonyl ligands of cyclopentadienyldicarbonyl(tetrahydrofuran)iron (II) tetrafluoroborate to form heteroligand complexes [CpFeL(CO)](+)BF(4)(−). The structural studies in the solid phase and in solutions showed that diazadiphosphacyclooctane ligands of all complexes adopted chair-boat conformations so that their nitrogen atoms were in close proximity to the central iron ion. The redox properties of the obtained complexes were performed by the cyclic voltammetry method. |
format | Online Article Text |
id | pubmed-7503606 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-75036062020-09-27 Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes Spiridonova, Yulia S. Nikolaeva, Yulia A. Balueva, Anna S. Musina, Elvira I. Litvinov, Igor A. Strelnik, Igor D. Khrizanforova, Vera V. Budnikova, Yulia G. Karasik, Andrey A. Molecules Article In order to synthesize new iron (II) complexes of 1,5-diaza-3,7-diphosphacyclooctanes with a wider variety of the substituents on ligands heteroatoms (including functionalized ones, namely, pyridyl groups) and co-ligands, it was found that these ligands with relatively small phenyl, benzyl, and pyridin-2-yl substituents on phosphorus atoms in acetonitrile formed bis-P,P-chelate cis-complexes [L(2)Fe(CH(3)CN)(2)](2+) (BF(4))(2)(−), whereas P-mesityl-substituted ligand formed only monoligand P,P-complex [LFe(CH(3)CN)(4)](2+) (BF(4))(2)(−). 3,7-dibenzyl-1,5-di(1′-(R)-phenylethyl)-1,5-diaza-3,7-diphosphacyclooctane reacted with hexahydrate of iron (II) tetrafluoroborate in acetone to give an unusual bis-ligand cationic complex of the composition [L(2)Fe(BF(4))](+) BF(4)(−), where two fluorine atoms of the tetrafluoroborate unit occupied two pseudo-equatorial positions at roughly octahedral iron ion, according to X-ray diffraction data. 1,5-diaza-3,7-diphosphacyclooctanes replaced tetrahydrofurane and one of the carbonyl ligands of cyclopentadienyldicarbonyl(tetrahydrofuran)iron (II) tetrafluoroborate to form heteroligand complexes [CpFeL(CO)](+)BF(4)(−). The structural studies in the solid phase and in solutions showed that diazadiphosphacyclooctane ligands of all complexes adopted chair-boat conformations so that their nitrogen atoms were in close proximity to the central iron ion. The redox properties of the obtained complexes were performed by the cyclic voltammetry method. MDPI 2020-08-19 /pmc/articles/PMC7503606/ /pubmed/32825126 http://dx.doi.org/10.3390/molecules25173775 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Spiridonova, Yulia S. Nikolaeva, Yulia A. Balueva, Anna S. Musina, Elvira I. Litvinov, Igor A. Strelnik, Igor D. Khrizanforova, Vera V. Budnikova, Yulia G. Karasik, Andrey A. Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes |
title | Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes |
title_full | Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes |
title_fullStr | Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes |
title_full_unstemmed | Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes |
title_short | Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes |
title_sort | synthesis and structure of iron (ii) complexes of functionalized 1,5-diaza-3,7-diphosphacyclooctanes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7503606/ https://www.ncbi.nlm.nih.gov/pubmed/32825126 http://dx.doi.org/10.3390/molecules25173775 |
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