Cargando…

Focusing on the Catalysts of the Pd- and Ni-Catalyzed Hirao Reactions

The Hirao reaction involving the phosphinoylation or phosphonation of aryl halides by >P(O)H reagents is a P–C bond forming transformation belonging to the recently very hot topic of cross-couplings. The Pd- or Ni-catalyzed variations take place via the usual cycle including oxidative addition, l...

Descripción completa

Detalles Bibliográficos
Autores principales:	Keglevich, György, Henyecz, Réka, Mucsi, Zoltán
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2020
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7503744/ https://www.ncbi.nlm.nih.gov/pubmed/32859095 http://dx.doi.org/10.3390/molecules25173897

Ejemplares similares

Experimental and Theoretical Study on the “2,2′-Bipiridyl-Ni-Catalyzed” Hirao Reaction of >P(O)H Reagents and Halobenzenes: A Ni(0) → Ni(II) or a Ni(II) → Ni(IV) Mechanism?
por: Keglevich, György, et al.
Publicado: (2020)

The Palladium Acetate‐Catalyzed Microwave‐Assisted Hirao Reaction without an Added Phosphorus Ligand as a “Green” Protocol: A Quantum Chemical Study on the Mechanism
por: Keglevich, György, et al.
Publicado: (2017)

New Developments on the Hirao Reactions, Especially from “Green” Point of View
por: Henyecz, Réka, et al.
Publicado: (2019)

Microwave-Assisted Ionic Liquid-Catalyzed Selective Monoesterification of Alkylphosphonic Acids—An Experimental and a Theoretical Study
por: Harsági, Nikoletta, et al.
Publicado: (2021)

Continuous Flow Esterification of a H-Phosphinic Acid, and Transesterification of H-Phosphinates and H-Phosphonates under Microwave Conditions
por: Kiss, Nóra Zsuzsa, et al.
Publicado: (2020)

Microwave-Assisted Palladium Acetate-Catalyzed C–P Cross-Coupling of Arylboronic Acids and >P(O)H Reagents in the Absence of the Usual Mono- and Bidentate P-Ligands: Mechanistic Insights
por: Huszár, Bianka, et al.
Publicado: (2023)

Microwaves as “Co-Catalysts” or as Substitute for Catalysts in Organophosphorus Chemistry
por: Keglevich, György
Publicado: (2021)

Preparation of 2-phospholene oxides by the isomerization of 3-phospholene oxides
por: Bagi, Péter, et al.
Publicado: (2020)

Pd-Catalyzed microwave-assisted synthesis of phosphonated 13α-estrones as potential OATP2B1, 17β-HSD1 and/or STS inhibitors
por: Jójárt, Rebeka, et al.
Publicado: (2018)

Synthesis and Reactions of α-Hydroxyphosphonates
por: Rádai, Zita, et al.
Publicado: (2018)

Pd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materials
por: Xu, Shiqing, et al.
Publicado: (2014)

The Kabachnik–Fields Reaction: Mechanism and Synthetic Use
por: Keglevich, György, et al.
Publicado: (2012)

Carbon-Supported Trimetallic Catalysts (PdAuNi/C) for Borohydride Oxidation Reaction
por: ElSheikh, Ahmed M. A., et al.
Publicado: (2021)

Synthesis of α-Aminophosphonates and Related Derivatives; The Last Decade of the Kabachnik–Fields Reaction
por: Varga, Petra R., et al.
Publicado: (2021)

Application of the Microwave Technique in Continuous Flow Processing of Organophosphorus Chemical Reactions
por: Bálint, Erika, et al.
Publicado: (2019)

Robust C-PdNi-CNF Sandwich-Structured Catalyst for Suzuki Reactions and Experimental Study on the Mechanism
por: Su, Yu, et al.
Publicado: (2022)

Pd/BIPHEPHOS is an Efficient Catalyst for the Pd‐Catalyzed S‐Allylation of Thiols with High n‐Selectivity
por: Schlatzer, Thomas, et al.
Publicado: (2019)

Recent Advances in Catalyzed Sequential Reactions and the Potential Use of Tetrapyrrolic Macrocycles as Catalysts
por: Santos, Everton Henrique, et al.
Publicado: (2018)

Facile Synthesis of Pd@PtM (M = Rh, Ni, Pd, Cu) Multimetallic Nanorings as Efficient Catalysts for Ethanol Oxidation Reaction
por: Wu, Xingqiao, et al.
Publicado: (2021)

Ni- and Ni/Pd-Catalyzed Reductive Coupling of Lignin-Derived Aromatics to Access Biobased Plasticizers
por: Su, Zhi-Ming, et al.
Publicado: (2023)

Sequential and iterative Pd-catalyzed cross-coupling reactions in organic synthesis
por: Dobrounig, Patrick, et al.
Publicado: (2016)

Asymmetric Henry Reaction of 2-Acylpyridine N-Oxides Catalyzed by a Ni-Aminophenol Sulfonamide Complex: An Unexpected Mononuclear Catalyst
por: Liu, Mouxiong, et al.
Publicado: (2019)

Synthesis of new Pro-PYE ligands as co-catalysts toward Pd-catalyzed Heck–Mizoroki cross coupling reactions
por: Munir, Naima, et al.
Publicado: (2019)

Enhancement Mechanism of Pt/Pd-Based Catalysts for Oxygen Reduction Reaction
por: Zhang, Xinqun, et al.
Publicado: (2023)

Tetraalkyl Hydroxymethylene-bisphosphonate and Dialkyl 1-Diphenylphosphinoyl-1-hydroxy-ethylphosphonate Derivatives by the Pudovik Reaction and Their Rearranged Products
por: Szalai, Zsuzsanna, et al.
Publicado: (2021)

Pd-Catalyzed Cross-Couplings: On the Importance of the Catalyst Quantity Descriptors, mol % and ppm
por: Horbaczewskyj, Christopher S., et al.
Publicado: (2022)

Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins
por: Obora, Yasushi, et al.
Publicado: (2010)

Effect of Binding Linkers on the Efficiency and Metabolite Profile of Biomimetic Reactions Catalyzed by Immobilized Metalloporphyrin
por: Balogh, György T., et al.
Publicado: (2022)

Synthesis of Ni(3)Si(4)O(10)(OH)(2) Porous Microspheres as Support of Pd Catalyst for Hydrogenation Reaction
por: Wang, Tingting, et al.
Publicado: (2019)

Nickel-catalyzed arylation of heteroaryl-containing diarylmethanes: exceptional reactivity of the Ni(NIXANTPHOS)-based catalyst
por: Cao, Xinyu, et al.
Publicado: (2016)

Rational Optimization of Supramolecular Catalysts for the Rhodium‐Catalyzed Asymmetric Hydrogenation Reaction
por: Daubignard, Julien, et al.
Publicado: (2017)

Organocatalytic Enantioselective Michael Reaction of Aminomaleimides with Nitroolefins Catalyzed by Takemoto’s Catalyst
por: Mu, Hongwen, et al.
Publicado: (2022)

Endo-Selective Pd-Catalyzed Silyl Methyl Heck Reaction
por: Parasram, Marvin, et al.
Publicado: (2014)

Investigation on the enhanced catalytic activity of a Ni-promoted Pd/C catalyst for formic acid dehydrogenation: effects of preparation methods and Ni/Pd ratios
por: Kim, Yongwoo, et al.
Publicado: (2018)

Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
por: Borhade, Sanjay R, et al.
Publicado: (2011)

Support Effects on the Activity of Ni Catalysts for the Propane Steam Reforming Reaction
por: Kokka, Aliki, et al.
Publicado: (2021)

Synthesis of Carbon-Supported PdIrNi Catalysts and Their Performance towards Ethanol Electrooxidation
por: Elsheikh, Ahmed, et al.
Publicado: (2021)

The Hydrolysis of Phosphinates and Phosphonates: A Review
por: Harsági, Nikoletta, et al.
Publicado: (2021)

Site Selectivity in Pd-Catalyzed Reactions of α-Diazo-α-(methoxycarbonyl)acetamides: Effects of Catalysts and Substrate Substitution in the Synthesis of Oxindoles and β-Lactams
por: Solé, Daniel, et al.
Publicado: (2019)

Comprehensive Experimental and Theoretical Study of the CO + NO Reaction Catalyzed by Au/Ni Nanoparticles
por: Kyriakou, Georgios, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_dnvch2u6oi9sr3ql8qt1grht8o